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Fetching data from CrossRef. Catalytically active dirhodium sheet-like coordination polymers are synthesized from their precursors via ligand exchange.
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Back to tab navigation. Go to our Instructions for using Copyright Clearance Center page for details. Aany Sofia Lilly Thankamony. The stability and reusability of the catalysts are verified by TG-DTA measurements and leaching tests.
If the material has been adapted instead of reproduced from the original RSC publication “Reproduced from” can be substituted with “Adapted from”. Residual trifluoroacetate species are investigated by quantitative 19 F MAS NMR which further reflects the configuration of trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure.
The article was received on 26 Apraccepted on 20 Sep and first published on 21 Sep Back to tab navigation Download options Please wait Information about reproducing material from RSC articles with different licences is available on our Permission Requests page. Search articles by author Jiquan Liu. DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process.
The catalysts show similar catalytic efficiency as the homogeneous catalyst in the model cyclopropanation between ethyl diazoacetate EDA and styrene.
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Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J. For reproduction of material from NJC: Reproduced material should be attributed as follows: Previous Article Next Article.
Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study.
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